Within the nuclear DFT approach, we determined the magnetic dipole and electric quadrupole moments for paired nuclear states corresponding to the proton (neutron) quasiparticles blocked in the π11/2− (ν13/2+) intruder configurations. We performed calculations for all deformed open-shell odd nuclei with 63 ≤ Z ≤ 82 and 82 ≤ N ≤ 126. Time-reversal symmetry was broken in the intrinsic reference frame and self-consistent shape and spin core polarizations were established. We determined spectroscopic moments of angular-momentum-projected wave functions and compared them with available experimental data. We obtained good agreement with data without using effective g-factors or effective charges in the dipole or quadrupole operators, respectively. We also showed that the intrinsic magnetic dipole moments, or those obtained for conserved intrinsic time-reversal symmetry, do not represent viable approximations of the spectroscopic ones.