A precise determination of the atomic mass of 75As has been performed utilizing the double Penning trap mass spectrometer, JYFLTRAP. The mass excess is measured to be −73035.519(42)keV/c2, which is a factor of 21 more precise and 1.3(9)keV/c2 lower than the adopted value in the newest Atomic Mass Evaluation (AME2020). This value has been used to determine the ground-state–to–ground-state electron-capture decay Q value of 75Se and β− decay Q value of 75Ge, which are derived to be 866.041(81) keV and 1178.561(65) keV, respectively. Using the nuclear energy-level data of 860.00(40) keV, 865.40(50) keV (final states of electron capture), and 1172.00(60) keV (final state of β− decay) for the excited states of 75As∗, we have determined the ground-state–to–excited-state Q values for two transitions of 75Se→75As∗ and one transition of 75Ge→75As∗. The ground-state–to–excited-state Q values are determined to be 6.04(41) keV, 0.64(51) keV, and 6.56(60) keV, respectively, thus confirming that the three low Q-value transitions are all energetically valid and one of them is a possible candidate channel for antineutrino mass determination. Furthermore, the ground-state–to–excited-state Q value of transition 75Se→75As∗ [865.40(50) keV] is revealed to be ultralow (<1 keV) and the first-ever confirmed electron capture transition possessing an ultralow Q value from direct measurements.