Bioinspired Mo, W and V complexes bearing a highly hydroxyl-functionalized Schiff base ligand
Finna-arvio
Bioinspired Mo, W and V complexes bearing a highly hydroxyl-functionalized Schiff base ligand
Bioinspired%20Mo%20W%20and%20V%20complexes%20bearing%20a%20highly%20hydroxyl-functionalized%20Schiff%20base%20ligand%20Inorganica%20Chimica%20Acta%20%20503%20119414.pdf
(Jyväskylän yliopisto - JYX / artikkelit)
A series of bioinspired dioxidomolybdenum(vi), dioxidotungsten(vi) and oxidovanadium(v) complexes [MoO2(H2LSaltris)], [WO2(H2LSaltris)] and [VO(HLSaltris)]2 were prepared by the reaction of a hydroxyl-rich Schiff base proligand N-(1,3-dihydroxy-2-(hydroxymethyl)propan-2-yl)-3,5-di-tert-butylsalicylaldimine (H4LSaltris) with metal precursors in methanol solutions. Molybdenum and tungsten complexes crystallize as mononuclear molecules, whereas the vanadium complex forms dinuclear units. From the complexes, [VO(HLSaltris)]2 shows activity in the oxidation of 4-tert-butylcatechol and 3,5-di-tert-butylcatechol, mimicking the action of the dicopper enzyme catechol oxidase.
Tallennettuna:
Kieli |
englanti |
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Sarja | Inorganica Chimica Acta |
Aiheet | |
ISSN |
0020-1693 |