Angular distributions of protons, deuterons, tritons and alpha-particles emitted from the reactions in the 2H+9Be-system at Elab=19.5 MeV were measured with an aim to shed light on the internal cluster structure of 9Be and the study of possible cluster transfer of 5He. The analyses suggest a significant contribution of five-nucleon transfer in the reaction channel 9Be(d,4He)7Li.