Solid‐state NMR Spectroscopy of Iodine(I) Complexes
Finna-arvio
Solid‐state NMR Spectroscopy of Iodine(I) Complexes
Chemistry An Asian Journal - 2023 - Ward - Solid‐state NMR Spectroscopy of Iodine I Complexes.pdf
(Jyväskylän yliopisto - JYX)
Solid-state NMR has been applied to a series of Barluenga-type iodine(I) [L-I-L]PF6 (L=pyridine, 4-ethylpyridine, 4-dimethylaminopyridine, isoquinoline) complexes as their hexafluorophosphate salts, as well as their respective non-liquid ligands (L), their precursor silver(I) complexes, and the respective N-methylated pyridinium and quinolinium hexafluorophoshate salts. These results are compared and contrasted to the corresponding solution studies and single-crystal X-ray structures. As the first study of its kind on the solid-state NMR behavior of halogen(I) complexes, practical considerations are also discussed to encourage wider utilization of this technique in the future.
Tallennettuna:
Kieli |
englanti |
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Sarja | Chemistry : An Asian Journal, 6 |
Aiheet | |
ISSN |
1861-4728 |