Extending the Series: Synthesis and Characterization of a Dicationic N-Heterocyclic Selenium Carbene Analogue
Finna-arvio
Extending the Series: Synthesis and Characterization of a Dicationic N-Heterocyclic Selenium Carbene Analogue
The room-temperature reaction between the Dipp2DAB ligand, SnCl2, and SeCl4 results in the quantitative formation of a dicationic N-heterocyclic “carbenoid”. This represents the first example of a chalcogenium dication that mimics the ubiquitous Arduengo-type carbenes; however, the electronic structure is significantly different.
Tallennettuna:
| Kieli |
englanti |
|---|---|
| Sarja | Journal of the American Chemical Society, 39 |
| Aiheet | |
| ISSN |
0002-7863 |