Self-assembly of M4L4 tetrahedral cages incorporating pendant P=S and P=Se functionalised ligands
Finna-arvio
Self-assembly of M4L4 tetrahedral cages incorporating pendant P=S and P=Se functionalised ligands
Herein, the synthesis of metal–organic tetrahedral cages featuring flexible thio- and selenophosphate-based ligands is described. The cages were prepared by sub-component self-assembly of A=P(OC6H4NH2-4)3 (A = S, Se) or S=P(SC6H4NH2-4)3,2-pyridinecarboxaldehyde, and either Fe[BF4]2 or Co[BF4]2. Preliminary host–guest studies into the ability of the pendant PQS and PQSe groups to interact with suitable substrates will be discussed.
Tallennettuna:
Kieli |
englanti |
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Sarja | Chemical Communications, 69 |
Aiheet | |
ISSN |
1359-7345 |